Tertiary Butyl Radical Of Butane | What Is The Formula For Tert-Butyl Radical?

by Chu Dung
02/07/2024

Tertiary Butyl Radical Of Butane | What Is The Formula For Tert-Butyl Radical?

What is the formula for tert-butyl radical?

tert-Butyl radical | C4H9 | CID 137103 – PubChem.

What is the structure of the tertiary butyl radical?

The structure of the tert-butyl radical has been investigated by means of ab initio restricted Hartree-Fock calculations using a split-valence basis set augmented by polarization functions. The radical is predicted to have a pyramidal C _3v ground state geometry with an out-of-plane bending angle of circa 10°.

What is tertiary butane?

tert-Butyl alcohol is the simplest tertiary alcohol, with a formula of (CH₃)₃COH (sometimes represented as t-BuOH). Its isomers are 1-butanol, isobutanol, and butan-2-ol. tert-Butyl alcohol is a colorless solid, which melts near room temperature and has a camphor-like odor.

What is tBu chemistry?

Tert-butyl (tert-butyl group; tBu): A portion of a molecular structure which is equivalent to 2-methylpropane minus one hydrogen atom from carbon 2. Sometimes abbreviated as tBu.

What is the formula for tert-butyl group?

If it connects at the central carbon, it is tertiary butyl, tert-butyl or t-butyl: −C(CH ₃) ₃ (preferred IUPAC name: tert-butyl)

Is tert-butyl the same as t-butyl?

t – butyl. In the third form, three of the carbons are single-bonded to a fourth carbon in the centre, and the rest of the molecule is attached to the centre carbon. In common names, this configuration is known as t-butyl or tert-butyl.

How do you find tertiary radicals?

Answer and Explanation: Tertiary radicals have radical carbons bonded to three R groups. Here, R is an alkyl group. The radical carbon has covalent bonding in the following structure with two alkyl carbons 1 and 2.

What is the structure of a tertiary radical?

Tertiary carbon radicals have three σ C-H bonds that donate, secondary radicals only two, and primary radicals only one. Therefore, tertiary radicals are the most stable and primary radicals the least stable.

What is tertiary butyl functional group?

t-Butyl Functional Group The third form has three of the carbons single bonded to a center fourth carbon and the rest of the molecule is attached to the center carbon. This configuration is called t-butyl or tert-butyl in common names. For systematic names, the longest chain is formed by carbons 2 and 1.

What is the formula for butane?

The molecular formula for butane is C4H10.

What is the alkyl radical of butane?

These alkyl groups have the formula C₄H₉. Two alkyl groups are derived from butane and two from isobutane. If a primary carbon atom of butane loses a hydrogen atom, an n-butyl group results; if a secondary carbon atom of butane loses a hydrogen atom, a secondary alkyl group, sec-butyl, forms.

What is the tertiary alcohol of butane?

tert-Butyl Alcohol is a colorless liquid or crystalline solid with a mothball-like odor. It is used in making flavors and perfumes, as a solvent for pharmaceuticals, a paint remover, and as an additive in unleaded gasoline. determine potentially hazardous exposures.

What is the difference between butane and butyl?

The molecular formula of butane is C₄H₁₀, while butyl has the molecular formula R – C₄H₉. Both compounds have the same number of carbon atoms, but the number of hydrogen atoms differs slightly. Butyl is missing one hydrogen atom.

Is Tbuok a strong nucleophile?

Tert-butoxide (tert-butoxide ion; tBuO^–): (CH₃)₃CO^–; the conjugate base of tert-butanol. A strong base (frequently used in E2 and enolate reactions) but a fairly poor nucleophile due to steric hindrance.

What is the other name for tertiary butanol?

Hence, the IUPAC name of tertiary butyl alcohol is 2-methyl-2-propanol. Q. Q.

What is TBU in chemistry?

Chemical Component Summary Name. TERTIARY-BUTYL ALCOHOL. Synonyms. 2-METHYL-2-PROPANOL.

What is tert-butyl also known as?

Tert-butyl group is named as:1,1-dimethylethyl1,3-dimethylethyl1,2-dimethylethyl1,2,3-trimethyyl.

Does tert butane exist?

Tert-butanol is a tertiary alcohol alcohol that is isobutane substituted by a hydroxy group at position 2. It has a role as a human xenobiotic metabolite. It derives from a hydride of an isobutane. tert-Butanol is a natural product found in Psidium guajava with data available.

Is iso butyl and tertiary butyl same?

Removing a hydrogen atom from a primary carbon atom of isobutane gives a primary alkyl group called the isobutyl group. Removing a hydrogen atom from the tertiary carbon atom of isobutane gives a tertiary alkyl group called the tert-butyl (t-butyl) group.

Why is tert-Butyl bromide?

tert-Butyl bromide is used as a raw material in synthetic organic chemistry. It is used to study the massive deadenylation of adenine based-nucleosides. Immiscible with water. Incompatible with strong bases and strong oxidizing agents.

Are tertiary radicals stable?

The alkyl radicals with different structures show different stabilities. Specifically, tertiary radical is most stable and the primary and methyl radicals are least stable, that follow the same trend as the stability of carbocations.

What are secondary and tertiary radicals?

Secondary free radicals are those in which Carbon is bonded with two alkyl or substituent groups. Tertiary free radicals are those in which carbon is bonded with three alkyl or substituent groups. Free electrons are having short life span as Carbon tends to complete its octet by gaining the electron.

What is a tertiary alkyl?

Tertiary alkyl halide (3^o alkyl halide; tertiary haloalkane; 3^o haloalkane): An alkyl halide (haloalkane) in which the halogen atom (F, Cl, Br, or I) is bonded to a tertiary carbon. Tert-butyl chloride (2-chloro-2-methylpropane), a typical tertiary alkyl halide.

What is a tertiary halide structure?

Finally, tertiary alkyl halides describe alkyl halides in which the carbon atom is bonded to the halogen and three other carbon atoms. An example of a tertiary alkyl halide is bromobutane which has the chemical formula C H 3 C H 3 C B r C H 3 .

What is tertiary line structure?

Tertiary structure refers to the ultimate three-dimensional conformation of a folded polypeptide chain, which involves the formation of structural or functional domains and the packing of amino acid side chains in a well-defined manner.

What is the formula for tert-butyl carbocation?

Tert-butyl carbocation: The tertiary (3^o) carbocation of molecular structure (CH₃)₃C⁺.

What is the formula for tert-butyl nitrite?

tert-Butyl nitrite | C4H9NO2 | CID 10906 – PubChem.

What is the formula for tert butoxide ion?

Tert-butoxide (tert-butoxide ion; tBuO^–): (CH₃)₃CO^–; the conjugate base of tert-butanol. A strong base (frequently used in E2 and enolate reactions) but a fairly poor nucleophile due to steric hindrance.

What is the notation for tert-butyl?

isobutyl: iBu. sec-butyl: s-Bu. tert-butyl: t-Bu.

Does n -butane have two ‘butyl’ groups?

The isomer n -butane can connect in two ways, giving rise to two “-butyl” groups: The second isomer of butane, isobutane, can also connect in two ways, giving rise to two additional groups: According to IUPAC nomenclature, “isobutyl”, ” sec -butyl”, and ” tert -butyl” used to be allowed retained names.

Is butyl a functional group?

Butyl is an organic functional group that derives from the compound butane. Butane is an organic compound that belongs to the alkane family. Butane is a molecule composed of four carbon atoms that are single-bonded to ten hydrogen atoms. Butyl’s roots can be traced back to butane.

What is the difference between butane and butyl?

Butane has the molecular formula C 4 H 10, whereas butyl has the molecular formula R – C 4 H 9. The number of carbon atoms is the same, but the number of hydrogen atoms differs slightly. Butyl appears to be missing one hydrogen atom.

Is tertiary butyl free radical more stable than methyl free radical?

We can interpret this to mean that the tertiary butyl free radical is more stable than the methyl free radical. (The term “free radical” or “radical” is used to mean an atom or group in which one of the bonding orbitals is occupied by a single electron. Radicals are normally uncharged.)

Alright, let’s dive into the world of tertiary butyl radicals and how they relate to butane. This might seem a bit complicated at first, but I’ll try to break it down in a way that makes sense.

Tertiary Butyl Radical – What is It?

Imagine a butane molecule, which is a chain of four carbon atoms (C) linked together with hydrogen atoms (H) attached to them. This is its basic structure:

“`
CH3-CH2-CH2-CH3
“`

Now, imagine we remove one of those hydrogen atoms. In its place, we have a single, unpaired electron. This is what makes it a radical, an atom or molecule with an unpaired electron. We call this specific radical a tertiary butyl radical.

Why “tertiary”? It’s all about the carbon atom that’s missing the hydrogen. We call a carbon atom primary if it’s bonded to one other carbon atom, secondary if it’s bonded to two other carbons, and tertiary if it’s bonded to three other carbons. In our tertiary butyl radical, the carbon with the unpaired electron is connected to three other carbons.

So, the tertiary butyl radical looks like this:

“`
CH3
|
CH3-C•
|
CH3
“`

Where the dot (•) represents the unpaired electron.

How it Forms

You can’t just pluck a hydrogen atom off a butane molecule and magically create a tertiary butyl radical. You need a bit of energy. The most common way is through a process called homolytic cleavage, where a chemical bond breaks in a way that each atom gets one of the bonding electrons.

Imagine shining ultraviolet light on butane. This light provides the energy to break a carbon-hydrogen bond in the butane molecule. The result? One hydrogen atom with an electron and a tertiary butyl radical with an unpaired electron.

Stability of the Tertiary Butyl Radical

This little radical is actually quite stable compared to other radicals. This is because it’s stabilized by hyperconjugation.

Hyperconjugation is a fancy term for electron delocalization. Think of it like this: the unpaired electron on the tertiary carbon can interact with the electrons in the carbon-hydrogen bonds of the three adjacent methyl groups (CH3). This interaction spreads the electron density, making the radical more stable.

Reactivity of the Tertiary Butyl Radical

While it’s stable, it’s still a radical, and radicals are reactive. They want to find another electron to pair up with. So, the tertiary butyl radical is eager to react with other molecules.

Common reactions:

Abstraction: It can steal a hydrogen atom from another molecule. This creates a new radical and a new molecule.
Addition: It can add to a double bond, creating a new carbon-carbon bond.
Coupling: Two tertiary butyl radicals can combine to form a dimer, a molecule with two tertiary butyl units connected by a carbon-carbon bond.

Importance of the Tertiary Butyl Radical

Tertiary butyl radicals play a role in many chemical processes, including:

Combustion: They are involved in the combustion of fuels, contributing to the production of heat and light.
Polymerization: They can initiate polymerization reactions, where monomers join together to form long chains.
Organic synthesis: They are used as building blocks in organic synthesis to create new and useful compounds.

FAQs about Tertiary Butyl Radical

Let’s address some common questions you might have:

Q: What is the difference between a primary, secondary, and tertiary radical?

A: The difference lies in the number of carbon atoms directly bonded to the carbon atom with the unpaired electron. Primary radicals are bonded to one carbon, secondary to two, and tertiary to three. Tertiary radicals are generally the most stable due to hyperconjugation.

Q: How does the tertiary butyl radical differ from the tertiary butyl cation?

A: The main difference lies in the charge. A tertiary butyl radical has an unpaired electron, making it neutral, while a tertiary butyl cation has a positive charge due to the loss of an electron. The tertiary butyl cation is also more stable than the tertiary butyl radical.

Q: What is the role of the tertiary butyl radical in the free radical halogenation of alkanes?

A: Tertiary butyl radicals are formed as intermediates in the free radical halogenation of alkanes, particularly when a tertiary hydrogen atom is present. The tertiary butyl radical is more stable than primary or secondary radicals, making it a more likely product.

Q: What is the mechanism of the tertiary butyl radical formation in the presence of UV light?

A: UV light provides the energy for homolytic cleavage of a carbon-hydrogen bond in a butane molecule. This process results in the formation of a hydrogen radical and a tertiary butyl radical.

Q: What are some examples of reactions involving the tertiary butyl radical?

A: The tertiary butyl radical can participate in various reactions, including:

Abstraction of hydrogen from alkanes: It can steal a hydrogen atom from an alkane, forming a new radical.
Addition to alkenes: It can add to a double bond, forming a new carbon-carbon bond.
Coupling with other radicals: Two tertiary butyl radicals can combine to form a dimer.

Remember, the tertiary butyl radical is a fundamental component in many chemical processes. Understanding its properties, formation, and reactivity is crucial for comprehending complex chemical reactions.

See more here: What Is The Structure Of The Tertiary Butyl Radical? | Tertiary Butyl Radical Of Butane

tert-Butyl radical | C4H9 | CID 137103 – PubChem

tert-Butyl radical | C4H9 | CID 137103 – structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, PubChem

tert-Butyl radical | C4H9 | ChemSpider

tert-Butyl radical. Molecular Formula CH. Average mass 57.114 Da. Monoisotopic mass 57.070423 Da. ChemSpider ID 120809. ChemSpider

Don’t Be Futyl, Learn The Butyls – Master Organic

There are four different types of “butyls”, and they all have their own name. In addition they each have a common name (“trivial Master Organic Chemistry

Butyl Group – Introduction, Butyl Structure, Preparation and Uses

Butane is a molecule composed of four carbon atoms that are single-bonded to ten hydrogen atoms. Butyl’s roots can be traced back to butane. Table of Contents. Butyl BYJU’S

Tert-butyl radical – NIST Chemistry WebBook

Tert-butyl radical. Formula: C 4 H 9. Molecular weight: 57.1143. CAS Registry Number: 1605-73-8. Information on this page: Gas phase ion energetics data. References. Notes. NIST Chemistry WebBook

1.33: Radical Reactions – Chemistry LibreTexts

The weakest (343 kJ/mol) is between the central carbon of a tertiary butyl group and a hydrogen atom. We can interpret this to mean that the tertiary butyl free Chemistry LibreTexts

9.3: Stability of Alkyl Radicals – Chemistry LibreTexts

Specifically, tertiary radical is most stable and the primary and methyl radicals are least stable, that follow the same trend as the stability of carbocations. This Chemistry LibreTexts

3.3: Alkyl Groups – Chemistry LibreTexts

explain what is meant by a primary, secondary, tertiary or quaternary carbon atom. represent the various types of organic compounds using the symbol “R” to represent any Chemistry LibreTexts

Is tertiary-butyl same as neo-butyl? – Chemistry Stack Exchange

Neo is a trivial prefix, which in the context of hydrocarbons, means two carbons bound to the same carbon (geminal) of the longest chain. The only hydrocarbon Chemistry Stack Exchange

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